The aim of our research group is to elucidate chemistry that takes place in the atmosphere, environment and at nanoscale level from the perspective of surface science. Surfaces are everywhere, which split nature into phases. For instance, approximately two-third of the earth’s surface is air-water interface. The chemical processes that occur at the interfacial region are in general different from that of the bulk (i.e. gas or liquid phase) chemistry. Therefore, it is of fundamental interest to understand surface phenomena. Using surface selective nonlinear laser spectroscopy, along with traditional spectroscopic methods of UV-Vis, fluorescence, IR, and Raman, we investigate the influence of surfaces on chemical processes relevant to atmospheric, environmental and nano-science.